Aldehyde
RCHO is the general formula for aldehydes, where R stands for an alkyl group or a hydrogen atom. The carbonyl group is joined to either an alkyl group or a hydrogen atom at the end of the carbon chain. The carbon atom in the carbonyl group has a trigonal planar shape and is sp2 hybridized.
Structure of Aldehyde
The structural formula of the Aldehyde is shown in the image below,
Aldehyde Properties
Aldehydes have unique chemical and physical characteristics. They are polar solvents like water-soluble, have a distinctively pungent smell, and have relatively low boiling temperatures in comparison to other organic compounds. Moreover, aldehydes are capable of a wide range of chemical processes, including nucleophilic addition, oxidation, and reduction.
Reactions of Aldehydes
Many chemical processes, such as nucleophilic addition, oxidation, and reduction, are possible with aldehydes.
Nucleophilic Addition
Aldehydes can engage in nucleophilic addition processes and are very reactive to nucleophiles. A nucleophile attacks the carbonyl group, which causes the creation of a new carbon-carbon bond. For instance, formaldehyde and ammonia can combine to create a primary amine.
Oxidation
Aldehydes can be oxidised to produce either pure carboxylic acids or a combination of alcohols and carboxylic acids. Aldehydes are often oxidised using the reagents potassium permanganate (KMnO4), chromic acid (H2CrO4), and silver nitrate (AgNO3).
Reduction
With reducing agents such as sodium borohydride (NaBH4) or lithium aluminium hydride, aldehydes can be converted to primary alcohols (LiAlH4). A new carbon-hydrogen bond is created when the carbonyl group is reduced to a hydroxyl group (-OH).
Applications of Aldehydes
Aldehydes have important applications in various industries such as,
- Production of plastics, dyes, and perfumes.
- Formaldehyde, the simplest aldehyde, is widely used as a disinfectant and preservative.
Oxidation of Aldehydes and Ketones
A carbonyl group (-C=O) is found at the end of a carbon chain, which distinguishes aldehydes from other organic molecules. They are often present in nature and have significant uses across several sectors. In this assignment, the structure, characteristics, and reactivity of aldehydes will be covered.
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