Aldehyde

RCHO is the general formula for aldehydes, where R stands for an alkyl group or a hydrogen atom. The carbonyl group is joined to either an alkyl group or a hydrogen atom at the end of the carbon chain. The carbon atom in the carbonyl group has a trigonal planar shape and is sp2 hybridized.

Structure of Aldehyde

The structural formula of the Aldehyde is shown in the image below,

 

Aldehyde Properties

Aldehydes have unique chemical and physical characteristics. They are polar solvents like water-soluble, have a distinctively pungent smell, and have relatively low boiling temperatures in comparison to other organic compounds. Moreover, aldehydes are capable of a wide range of chemical processes, including nucleophilic addition, oxidation, and reduction.

Reactions of Aldehydes

Many chemical processes, such as nucleophilic addition, oxidation, and reduction, are possible with aldehydes.

Nucleophilic Addition

Aldehydes can engage in nucleophilic addition processes and are very reactive to nucleophiles. A nucleophile attacks the carbonyl group, which causes the creation of a new carbon-carbon bond. For instance, formaldehyde and ammonia can combine to create a primary amine.

Oxidation

Aldehydes can be oxidised to produce either pure carboxylic acids or a combination of alcohols and carboxylic acids. Aldehydes are often oxidised using the reagents potassium permanganate (KMnO4), chromic acid (H2CrO4), and silver nitrate (AgNO3).

Reduction

With reducing agents such as sodium borohydride (NaBH4) or lithium aluminium hydride, aldehydes can be converted to primary alcohols (LiAlH4). A new carbon-hydrogen bond is created when the carbonyl group is reduced to a hydroxyl group (-OH).

Applications of Aldehydes

Aldehydes have important applications in various industries such as,

  • Production of plastics, dyes, and perfumes. 
  • Formaldehyde, the simplest aldehyde, is widely used as a disinfectant and preservative.

Oxidation of Aldehydes and Ketones

A carbonyl group (-C=O) is found at the end of a carbon chain, which distinguishes aldehydes from other organic molecules. They are often present in nature and have significant uses across several sectors. In this assignment, the structure, characteristics, and reactivity of aldehydes will be covered.

Similar Reads

Aldehyde

RCHO is the general formula for aldehydes, where R stands for an alkyl group or a hydrogen atom. The carbonyl group is joined to either an alkyl group or a hydrogen atom at the end of the carbon chain. The carbon atom in the carbonyl group has a trigonal planar shape and is sp2 hybridized....

Ketones

A carbonyl group (-C=O) is found in the centre of a carbon chain, which distinguishes ketones from other organic molecules. Due to the carbonyl group’s attachment to two additional carbon atoms, ketones have unique chemical and physical characteristics....

Carboxylic Acids

A carboxyl group (-COOH) is joined to a carbon atom in a family of chemical molecules known as carboxylic acids. The carbonyl group (-C=O) and the hydroxyl group (-OH) are both connected to the same carbon atom in the carboxyl group, which is what gives carboxylic acids their distinguishing characteristics....

Oxidation Reaction

A chemical reaction called oxidation occurs when an atom, molecule, or ion loses electrons or experiences an increase in oxidation status. This procedure can be carried out either by removing hydrogen atoms from a molecule or by reacting with an oxidising substance like oxygen or hydrogen peroxide....

Applications of Oxidation Reaction

Aldehydes, ketones, and carboxylic acids may be oxidised, and this process has several industrial uses. For instance, the creation of carboxylic acids, which are extensively employed in the pharmaceutical and food sectors, is accomplished via the oxidation of aldehydes and ketones. Carbon dioxide, a crucial gas utilised in several industrial processes, is created by the oxidation of carboxylic acids....

FAQs on Aldehydes and Ketones

Q1: What are the chemical structures of Aldehydes, Ketones and Carboxylic Acids?...

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